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Contents • • • • • • • • • • • • • • • • • • • • • • • • • Physical and chemical properties In purer forms, crack rocks appear as off-white nuggets with jagged edges, with a slightly higher density than candle wax. Purer forms of crack resemble a hard brittle plastic, in crystalline form (snaps when broken). A crack rock acts as a (see: ), numbing the tongue or mouth only where directly placed. Purer forms of crack will sink in water or melt at the edges when near a flame (crack vaporizes at 90 °C, 194 °F). Crack cocaine as sold on the streets may be or 'cut' with other substances mimicking the appearance of crack cocaine to increase bulk. Use of toxic adulterants such as has been documented. A close up of the 'cooking' process that creates crack.

(NaHCO 3, common baking soda) is a base used in preparation of crack, although other may substitute for it. The net reaction when using sodium bicarbonate is Coc-H +Cl − + NaHCO 3 → Coc + H 2O + CO 2 + NaCl With: Coc-H +Cl − + NH 4HCO 3 → Coc + + CO 2 + H 2O With: 2(Coc-H +Cl −) + (NH 4) 2CO 3 → 2 Coc + 2 NH 4Cl + CO 2 + H 2O Crack cocaine is frequently purchased already in rock form, although it is not uncommon for some users to 'wash up' or 'cook' powder cocaine into crack themselves. This process is frequently done with baking soda (sodium bicarbonate), water, and a spoon. Once mixed and heated, the bicarbonate reacts with the hydrochloride of the powder cocaine, forming free base cocaine and (H 2CO 3) in a reversible acid-base reaction. The heating accelerates the degradation of carbonic acid into (CO 2) and water. Loss of CO 2 prevents the reaction from reversing back to cocaine hydrochloride. Free base cocaine separates as an oily layer, floating on the top of the now leftover aqueous phase.